There are different grades of plywood. That would be a good start to your hood. You can get oak, birch, poplar, spf plywood. Each has their own appealing characteristics.
You can trim the hood with various moldings as well. Fluted casing gives a nice formal look. You can use quarter round, cove, outside corners, rosettes, plinths, crown, etc. It is only limited by your imagination and creativity.
The inside of the canopy can be finished with Kilz or an equivalent primer that will seal out humidity.
Oh, you should also use stainless steel screws.
swimmer