hi.
Topping off is also continous, just like rain. I don't have a specific number, but the mean time of hydrologic cycle is much longer than one topping off a small, open top aquarium.
My comments are not arguments either. I just want to point out how little the atomsphere hold, and why the pollution due to rain on the ocean is a minor concern compare to using rain water as top off. River runoffs enriched by terrestrial activities (industrial waste, agricultural waste) are more of a concern than rain water effect on the ocean.
Depends on how close do you live near a industrial plant and other factors, it may be fine to use rainwater if you filter it thru activated carbon. The fact of the matter is that the quality of rainwater is very difficult to control, and pollutants travels thousands of miles. My personal option, FWIW, is that rainwater should be saved for garden, not reef. If one feels bad about waste water from RO, just drain the brine out to the garden or washing machine, etc..