As others have mentioned - decrease nutrient import - ie. make sure you're not overfeeding, use purified source water, don't dose unnecessary additives/liquid foods, etc., thaw/rinse frozen foods before adding to the tank (the juices are loaded with phosphates), limit use of phosphate rich foods like flake, golden pearls, etc.
Also, as mentioned, increase nutrient export - ie. better skimming, water changes, activated carbon use, etc. Make sure you have a few grazers in there that will eat the stuff (but don't go crazy adding a ton of animals that will later starve once the problem is under control).
Another helpful thing - blast the rockwork periodically with a turkey baster or powerhead. Syphon out the resulting crap when you do a water change. If you're doing all of this stuff, it's just a matter of time before you overcome it. :wink:
HTH