I used to be a kalk user, I had precip buildup in my bucket. Never had any black film, but would suggest to clean and rinsed the bucket everytime you make a new mix.
It could be some type of comtaminate. I'd dump that mix.
Yeah, I dumped the remainder, wiped it down with paper towel paper, and added new mix.. Also noticed the phosphates went back up..
Anyone dosing vinegar and Kalk???
i do, and i dont get any slime, but i also have 2 containers i switch out and clean, fill one up with ro and day before i have to switch top off i mix the kalk and vinegar, if anything i have a white residue