Someone could write a text book trying to answer that question...
For starters
RTN = rapid tissue necrosis.
STN = slow tissue necrosis
A number of issues can cause either. But the big difference RTN can wipe out a colony in a few hours. STN takes days.
RTN/STN are usually brought on by stress, wether its from shipping, poor water quality, unstable water parameters like temp fluctuation, Kh swings, low calcium, global warming, ocean acidification, rising sea temps... The list goes on and on.
RTN is quick, like a matter of a few hours and the whole coral could be gone
STN is a slower process