My tanks have a very slight shift, usually .2 or so lower in the morning before lights on than what would be found in the evening just before lights go off. no big deal for the corals, but a friend of mine was having greater fluxes of 7.9-8.4 (hand held pH unit) in her 5 g between the day and night cycles and it was also heavily stocked with fish--we thought this required greater buffer support than usual.
pH shifts between the night and day phase is common in reef tanks, with some reporting greater variances in heavily stocked tanks (relative to water column) and especially in tanks where the macro algae is lit under the same schedule as the display tank. One way to resolve that is to alternately light or continually light a refugium. Unless you dose alkalinity at night a few hours after the lights go off, or have better-than-average circulation, it is likely that you too have the same shift but can't tell because of the test kits you use (colored reagents?) This slight shift is a very common occurence in most setups and less pronounced in others, but either way the shift is there to some degree unless you specifically address the -net- production of CO2 from plants/animals during the night phase