My best advice is to look at any recent changes, especially if the buildup happened very suddenly. An overflow is the best way I know of to get rid of the surface film, the skimmer should pull it out for removal. You should have the powerheads pointed towards the surface anyway, to boost O2/CO2 exchange at the surface.
A few other things to consider: if using tap water, is it possible your water district may have made some changes?
Has the sun changed position enough to expose the tank to brighter light, or lengthened the time it gets bright light?
Have you experienced any die-offs?
Do your bulbs need changing, perhaps?
New food or feeding regimen?