Who told you that? It is true that kalk will bind with PO4 and heavy metal but only at high conc. and form a precipitate when you mix it to make your topoff soln. That's why you should leave the solid stuff behind and only use the kalk solution. Once it is in the tank, the solution gets diluted very quickly and if it does bind with something in the tank water, it should precipitate out of solution and why would it bind PO4 preferential to the live rock.
Its true when i started using zoevita there was a forum that give a break down what kalk does to po4 and why not to use it . Do some reseach on kalk and you well see how bad it is to use it.
Here read this.
Greetings All !
Kalkwasser precipitates phosphate out of solution, creating what is, in effect, a "phosphate reservoir" within the system. Changes in the pH of microhabitats where these precipitates settle can cause phosphate to be released back into solution. Since the ZEOvit system is designed to export phosphate, adding something which creates a reservoir is considered counter-productive.
Dr. Albert Thiel wrote a description of this process, with specific regard to "unexplained" algae blooms. Some quotes ...
It has been postulated, and proven, that the long term use of Kalkwasser precipitates phosphates out of the water (which Kalkwasser really does by the way) and that these phosphate based compounds settle "on" and "in" the rock (live rock) in the aquarium, as well as "in" and "on" the substrate that may be present in the aquarium.
... Phosphates that are "bound" in an insoluble form and are, therefore, not available to algae "can" and "will" go into solution because of pH fluctuations in certain areas of the aquarium, areas where a much lower pH exists or develops, than the actual pH of the aquarium itself.
... When the pH drops in those areas of the aquarium, these insoluble compounds break up. Because they are in low pH areas the compounds dissociate, resulting in ortho-phosphate that goes back into solution, giving rise to the sudden appearance of micro-algae growth, a growth that was totally "unexpected" and "unpredictable" given the tank's water quality conditions ... .
Extracted from:
Sudden and Unexplained Micro-Algae Outbreaks (
http://www.netpets.org/fish/reference/reefref/algaeoutbrk.html)
Dr. Albert Thiel